A thermally robust di-n-butyl thorium complex with an unstable dimethyl analogue.
نویسندگان
چکیده
Methyl and n-butyl thorium complexes of a rigid 2,6-bis(anilidomethyl)pyridine ligand have been prepared; the n-butyl complex is thermally stable, even at 60 degrees C, while the methyl complexes exhibit a high tendency to eliminate methane via sigma-bond metathesis.
منابع مشابه
Crystal structure of the tetrahydrofuran disolvate of a 94:6 solid solution of [N 2,N 6-bis(di-tert-butylphosphanyl)pyridine-2,6-diamine]dibromidomanganese(II) and its monophosphine oxide analogue
The MnBr2 complex of N2,N6-bis-(di-tert-butyl-phosphan-yl)pyridine-2,6-di-amine (1·MnBr2) co-crystallizes with 5.69% of the monophosphine oxide analogue (1O·MnBr2) and two tetra-hydro-furan (THF) mol-ecules, namely [N2,N6-bis-(di-tert-butyl-phosphan-yl)pyridine-2,6-di-amine]-dibromido-manganese(II)-[bis-(di-tert-butyl-phosphan-yl)({6-[(di-tert-butyl-phosphan-yl)amino]-pyridin-2-yl}amino)-phosph...
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ورودعنوان ژورنال:
- Dalton transactions
دوره 39 29 شماره
صفحات -
تاریخ انتشار 2010